當glue為動詞時，有「粘貼」的意思，是否可以與stick互換？

不能互換。而且glue多用作「名詞」，或者用「動詞ed」形式，作表語。如最後一個例子，不是被動語態。

stick 1 v. S1 W3 / st?k ; st?k / 英 / st?k /

( past tense and past participle stuck 1 ATTACH 粘貼 [I,T] to attach something to something else using a substance, or to become attached to a surface 粘，

This stamp won』t stick properly. 這張郵票貼不牢。

stick sth on/to/in etc sth

Someone had stuck posters all over the walls.

有人把海報貼滿了牆。

[+ to/together ]

I could feel my shirt sticking to my back. 我能感覺到襯衫貼在了背上。

The oil keeps the pasta from sticking together.

油可避免義大利面粘在一起。

glue 1 n. [C,U] / ɡlu? ; glu / 英 / ɡlu? /

1 a sticky substance used for joining things together 膠，膠水

They are all glued to the Olympic Games. 他們都全神貫注於奧運會。