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目前的科技水平還是無法迫使氦發生化學反應?


Helium has a valence of zero and is chemically unreactive under all normal conditions.

[44]

It is an electrical insulator unless ionized. As with the other noble gases, helium has metastable energy levels that allow it to remain ionized in an electrical discharge with a voltage below its ionization potential.

[5]

Helium can form unstable compounds, known as excimers, with tungsten, iodine, fluorine, sulfur and phosphorus when it is subjected to an electric glow discharge, to electron bombardment, or else is a plasma for another reason. The molecular compounds HeNe, HgHe10, and WHe2, and the molecular ions He+ 2, He2+

2, HeH

+

, and HeD

+

have been created this way.

[61]

HeH

+

is also stable in its ground state, but is extremely reactive—it is the strongest Br?nsted acid known, and therefore can exist only in isolation, as it will protonate any molecule or counteranion it comes into contact with. This technique has also allowed the production of the neutral molecule He2, which has a large number of band systems, and HgHe, which is apparently held together only by polarization forces.

[5]

Theoretically, other true compounds may also be possible, such as helium fluorohydride (HHeF) which would be analogous to HArF, discovered in 2000.

[62]

Calculations show that two new compounds containing a helium-oxygen bond could be stable.

[63]

Two new molecular species, predicted using theory, CsFHeO and N(CH3)4FHeO, are derivatives of a metastable [F– HeO] anion first theorized in 2005 by a group from Taiwan. If confirmed by experiment, such compounds will end helium"s chemical inertness, and the only remaining inert element will be neon.

[64]

Helium has been put inside the hollow carbon cage molecules (the fullerenes) by heating under high pressure. The endohedral fullerene molecules formed are stable up to high temperatures. When chemical derivatives of these fullerenes are formed, the helium stays inside.

[65]

If helium-3 is used, it can be readily observed by helium nuclear magnetic resonance spectroscopy.

[66]

Many fullerenes containing helium-3 have been reported. Although the helium atoms are not attached by covalent or ionic bonds, these substances have distinct properties and a definite composition, like all stoichiometric chemical compounds.


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